Metallophilic interactions in iodido(2,2':6',2''-terpyridine)platinum(II) diiodidoaurate(I).

نویسندگان

  • Christina S Angle
  • Kathryn J Woolard
  • Michael I Kahn
  • James A Golen
  • Arnold L Rheingold
  • Linda H Doerrer
چکیده

In the title compound, [PtI(C(15)H(11)N(3))][AuI(2)], the [PtI(terpy)](+) cations (terpy is 2,2':6',2''-terpyridine) stack in pairs about inversion centers through Pt...Pt interactions of 3.5279 (5) A. The [AuI(2)](-) anions also exhibit pairwise stacking, with Au...I distances of 3.7713 (5) A. The [PtI(terpy)](+) cations and [AuI(2)](-) anions aggregate forming infinite arrays of stacked ...([[PtI(terpy)](+)...[PtI(terpy)](+)]...[[AuI(2)](-)...[AuI(2)](-)])... units.

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منابع مشابه

Bromido(2,2′:6′,2′′-terpyridine)platinum(II) dibromidoaurate(I) dimethyl sulfoxide solvate

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عنوان ژورنال:
  • Acta crystallographica. Section C, Crystal structure communications

دوره 63 Pt 6  شماره 

صفحات  -

تاریخ انتشار 2007